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Symmetry Lab › S4 › 1,3,5,7-Tetramethylcyclo-octatetraene (methyl C shown)

C₈H₄(CH₃)₄ 1,3,5,7-Tetramethylcyclo-octatetraene (methyl C shown)

Tub with four methyls · point group S4 · order 4

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Point group
S4 — An S4 improper rotation axis (rotate, then reflect) with no mirror plane; it contains a C2 axis.
Order
4
Operations
E, S₄, C₂, S₄³
Shape
Tub with four methyls
Atoms
16 (C × 12, H × 4)

Symmetry elements of C₈H₄(CH₃)₄

  • S₄ — rotate 90° about the tub axis, then reflect
  • C₂ — the tub axis (S₄²)

Structure

  • Ring C=C 1.34 Å, C–C 1.48 Å
  • Methyl on every second carbon
  • The methyls kill the C₂′ axes and σd planes of the tub; only S₄ (and C₂) remain
1,3,5,7-Tetramethylcyclo-octatetraene (methyl C shown) (C8H4(CH3)4) — S4 symmetry elements
1,3,5,7-Tetramethylcyclo-octatetraene (methyl C shown): symmetry elements of the S4 point group

Open in the 3D lab →  ·  All S4 molecules  ·  All point groups