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Symmetry Lab › D6 › Bis(benzene)chromium, twisted by 15°

Cr(C₆H₆)₂ (twisted) Bis(benzene)chromium, twisted by 15°

Sandwich, rings twisted by 15° · point group D6 · order 12

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Point group
D6 — A C6 principal axis and 6 C2 axes perpendicular to it, with no mirror plane. Molecules in this group are chiral.
Order
12
Operations
E, 5C6, 6C₂ (rotations only)
Shape
Sandwich, rings twisted by 15°
Atoms
25 (Cr, C × 12, H × 12)

Symmetry elements of Cr(C₆H₆)₂ (twisted)

  • C₆ — the main axis
  • C₂ (1) — perpendicular to the ring axis, halfway between the two rings’ atoms
  • C₂ (2) — perpendicular to the ring axis, halfway between the two rings’ atoms
  • C₂ (3) — perpendicular to the ring axis, halfway between the two rings’ atoms
  • C₂ (4) — perpendicular to the ring axis, halfway between the two rings’ atoms
  • C₂ (5) — perpendicular to the ring axis, halfway between the two rings’ atoms
  • C₂ (6) — perpendicular to the ring axis, halfway between the two rings’ atoms

Structure

  • Cr–C 2.15 Å
  • Rings turned 15°
  • Only rotations survive: D6
Bis(benzene)chromium, twisted by 15° (Cr(C6H6)2 (twisted)) — D6 symmetry elements
Bis(benzene)chromium, twisted by 15°: symmetry elements of the D6 point group

Open in the 3D lab →  ·  All D6 molecules  ·  All point groups