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Symmetry Lab › D∞h › Dicyanoaurate(I) ion

[Au(CN)₂]⁻ Dicyanoaurate(I) ion

Linear · point group D∞h · order ∞

Open [Au(CN)₂]⁻ in 3D →

Point group
D∞h — A linear molecule with a centre of inversion: the C∞ axis, the planes containing it, a perpendicular mirror plane and an infinite number of perpendicular C2 axes.
Order
∞
Operations
E, 2C∞, ∞σᵥ, i, 2S∞, ∞C₂
Shape
Linear
Atoms
5 (N × 2, C × 2, Au)

Symmetry elements of [Au(CN)₂]⁻

  • C∞ — the molecular axis: any rotation leaves the molecule unchanged
  • σᵥ (one of ∞) — any plane containing the axis
  • σᵥ (another) — any plane containing the axis
  • i — centre of inversion
  • σh — perpendicular to the axis, through the centre
  • C₂ (one of ∞) — any line through the centre perpendicular to the axis
  • C₂ (another) — same, at right angles
  • S∞ — any rotation about the axis, then reflect in σh

Structure

  • Au–C 1.98 Å, C≡N 1.15 Å
  • Linear d¹⁰ gold(I)
  • The ion in gold cyanidation
Dicyanoaurate(I) ion ([Au(CN)2]-) — D∞h symmetry elements
Dicyanoaurate(I) ion: symmetry elements of the D∞h point group

Other D∞h molecules

Open in the 3D lab →  ·  All D∞h molecules  ·  All point groups