Skip to content

Symmetry Lab › D3h › Sulfur trioxide

SO₃ Sulfur trioxide

Trigonal planar · point group D3h · order 12

Open SO₃ in 3D →

Point group
D3h — A C3 principal axis, 3 perpendicular C2 axes and a horizontal mirror plane; these also give 3 vertical planes.
Order
12
Operations
E, 2C₃, 3C₂, σh, 2S₃, 3σᵥ
Shape
Trigonal planar
Atoms
4 (S, O × 3)

Symmetry elements of SO₃

  • C₃ — perpendicular to the plane of three O atoms
  • C₂ (1) — along one S–O bond
  • C₂ (2) — along one S–O bond
  • C₂ (3) — along one S–O bond
  • σh — the plane of the three O atoms
  • σᵥ (1) — contains the C₃ axis and one bond
  • σᵥ (2) — contains the C₃ axis and one bond
  • σᵥ (3) — contains the C₃ axis and one bond
  • S₃ — rotate 120°, then reflect in σh

Structure

  • S=O 1.420 Å
  • O–S–O 120°
  • No lone pair on S
Sulfur trioxide (SO3) — D3h symmetry elements
Sulfur trioxide: symmetry elements of the D3h point group

Other D3h molecules

Open in the 3D lab →  ·  All D3h molecules  ·  All point groups