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Symmetry Lab › Td › Xenon tetroxide

XeO₄ Xenon tetroxide

Tetrahedral · point group Td · order 24

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Point group
Td — The full symmetry of a regular tetrahedron: four C3 axes, three C2 axes (each also an S4 axis) and six dihedral mirror planes. There is no centre of inversion.
Order
24
Operations
E, 8C₃, 3C₂, 6S₄, 6σd
Shape
Tetrahedral
Atoms
5 (Xe, O × 4)

Symmetry elements of XeO₄

  • C₃ (1) — along one Xe–O bond
  • C₃ (2) — along one Xe–O bond
  • C₃ (3) — along one Xe–O bond
  • C₃ (4) — along one Xe–O bond
  • C₂ (x) — bisects two bond angles; also an S₄ axis
  • C₂ (y) — bisects two bond angles; also an S₄ axis
  • C₂ (z) — bisects two bond angles; also an S₄ axis
  • S₄ (x) — rotate 90°, then reflect
  • S₄ (y) — rotate 90°, then reflect
  • S₄ (z) — rotate 90°, then reflect
  • σd (1) — contains Xe and two ligands
  • σd (2) — contains Xe and two ligands
  • σd (3) — contains Xe and two ligands
  • σd (4) — contains Xe and two ligands
  • σd (5) — contains Xe and two ligands
  • σd (6) — contains Xe and two ligands

Structure

  • Xe=O 1.736 Å
  • O–Xe–O 109.5°
  • No lone pair on Xe
Xenon tetroxide (XeO4) — Td symmetry elements
Xenon tetroxide: symmetry elements of the Td point group

Other Td molecules

Open in the 3D lab →  ·  All Td molecules  ·  All point groups