ABC26IN0230 · Organometallic Compounds

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: 18 Electron Rule · Exam: CSIR-NET 2011 · Marks: 2 · Difficulty: Hard

A compound A having the composition $\mathrm{FeC_9H_8O_3}$ shows one signal at 2.5 ppm and another one around 5.0 ppm in its ${}^{1}\mathrm{H}$ NMR spectrum. The IR spectrum of this compound shows two bands around $1680\,\mathrm{cm^{-1}}$. The compound follows the 18 electron rule of the following statements for A, the correct one is/are (A) It has $\eta^{5}\text{-}\mathrm{Cp}$ group. (B) It has a terminal CO ligand. (C) It has a $\mathrm{CH_3}$ ligand (D) It has Fe-H bond.
(a)(A) and (B) only
(b)(C) only
(c)(A) and (C) only
(d)(B) and (D) only
Answer
Answer (as printed): A
Explanation
No explanation was printed for this question.

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