ABC26IN0619 · Coordination Chemistry

Subject: Inorganic Chemistry · Chapter: Coordination Chemistry · Topic: Coordination Compounds – General · Exam: JAM 2005-2022 · Marks: 2 · Difficulty: Medium

The magnetic moment of $\left[\mathrm{Fe}(\mathrm{phen})_{2}(\mathrm{NCS})_{2}\right]$ varies with temperature. The magnetic moments at 200 K and 50 K are 4.9 BM and 0 BM, respectively. Write the d-electron configurations of Fe at both temperatures and give reason for the observed change in the magnetic moment (phen = 1,10-phenanthroline).
Answer
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