ABC26IN1364 · Organometallic Compounds
Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: 18 Electron Rule · Exam: NET JUNE 2012 · Marks: 2 · Difficulty: Easy
The complex that DOES NOT obey 18 - electron rule is:
(a)$\left[\left(\eta^{5}-\mathrm{C}_{5} \mathrm{H}_{5}\right) \mathrm{RuCl}(\mathrm{CO})\left(\mathrm{PPh}_{3}\right)\right]$
(b)$\left[\mathrm{W}(\mathrm{CO})_{3}\left(\mathrm{SiMe}_{3}\right)(\mathrm{Cl})(\mathrm{NCMe})_{2}\right]$
(c)$\left[\mathrm{IrCl}_{3}\left(\mathrm{PPh}_{3}\right)_{2}(\mathrm{AsPh}_{2})_{2}\right]^{-}$
(d)$\left[\mathrm{Os}(\mathrm{N}) \mathrm{Br}_{2}\left(\mathrm{PMe}_{3}\right)\left(\mathrm{NMe}_{2}\right)\right]^{-}$
Answer
Explanation
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