ABC26IN1442 · Organometallic Compounds
Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Organometallic Compounds – General · Exam: NET DEC 2015 · Marks: 2 · Difficulty: Medium
In the following reaction sequence \[ \begin{array}{l} \mathrm{HNEt}_{2}+\mathrm{CS}_{2} \xrightarrow{\mathrm{KOH}} \mathrm{P} \xrightarrow{\text{aq. soln}} \mathrm{R} \\ \mathrm{I}_{2} \xrightarrow{[\mathrm{CpMo(CO)_3}]_2} \mathrm{S} \end{array} \]
Where dtc = dithiocarbamate and tds = thiuramdisulfide. Identify P, R and S. Cp$=\eta^{5}\text{-}\mathrm{C_5H_5}$ | P | R | S |
|---|
| (a) | $\mathrm{Et_2dtc^{-}K^{+}}$ | $\mathrm{Et_4tds}$ | $\mathrm{CpMo(Et_2dtc)(CO)_2}$ |
| (b) | $\mathrm{Etdtc^{-}K^{+}}$ | $\mathrm{Et_3tds}$ | $\mathrm{CpMo(Et_3dtc)(CO)_2}$ |
| (c) | $\mathrm{Et_4dtc^{-}K^{+}}$ | $\mathrm{Et_2tds}$ | $\mathrm{CpMo(Et_4dtc)(CO)}$ |
| (d) | $\mathrm{Etdtc^{-}K^{+}}$ | $\mathrm{Ettdc}$ | $\mathrm{CpMo(Etdtc)(Co)}$ |
Answer
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Explanation
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