ABC26OR0338 · Reagents Reaction Mechanisms and Named Reactions

Subject: Organic Chemistry · Chapter: Reagents Reaction Mechanisms and Named Reactions · Topic: Reagents, Reaction Mechanisms & Named Reactions – General · Exam: CSIR-NET JUNE 2017 · Marks: 2 · Difficulty: Medium

The correct combination of reagents A and B to effect the following transformations are structure <- B <- structure -- A --> structure
(a)A = cat.OsO4, NMO B = i) $\mathrm{I_{2}}$, PhCO2Ag ii) aq.NaOH
(b)A = alkaline $\mathrm{KMnO_{4}}$ B = i) $\mathrm{I_{2}}$, PhCO2Ag, $\mathrm{H_{2}O}$ ii) aq.NaOH
(c)A = i) $\mathrm{I_{2}}$, PhCO2Ag ii) aq.NaOH B = cat $\mathrm{OsO_{4}}$, TMEDA, NMO
(d)A = m-CPBA, ii) aq.NaOH B = alkaline $\mathrm{KMnO_{4}}$
Answer
Answer (as printed): B
Explanation
The reaction is shown below:

Explanation as extracted from the printed page; notation may be imperfect.

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