ABC26OR1056 · Pericyclic Reactions

Subject: Organic Chemistry · Chapter: Pericyclic Reactions · Topic: Cycloaddition Diels Alder · Exam: NET JUNE 2018 · Marks: 2 · Difficulty: Hard

For the following thermal $[2+2]$ cycloaddition reaction, the correct statement about Transition State (TS) and preference for endo product formation is structure structure structure
(a)TS: $\pi 2 \mathrm{s}+\pi 2 \mathrm{s}$; Me > i-Pr > t-Bu
(b)TS: $\pi 2s + \pi 2a$; t-Bu > i-Pr > Me
(c)TS: $\pi 2s + \pi 2a$; Me > i-Pr > t-Bu
(d)TS: $\pi 2 \mathrm{s}+\pi 2 \mathrm{s} ; \mathrm{t}-\mathrm{Bu}>\mathrm{i}-\mathrm{Pr}>\mathrm{Me}$
Answer
Answer (as printed): A
Explanation
No explanation was printed for this question.

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