Question Bank › Physical Chemistry › Concentration B B › ABC26PH0365ABC26PH0365 · Concentration B B Subject: Physical Chemistry · Chapter: Concentration B B · Topic: Concentration B B – General · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Medium
The temperature dependence of partition are as follows: \[ \begin{array}{ll} \mathrm{q}_{\text{translation}} \propto \mathrm{T}^{3/2} & \mathrm{q}_{\text{vibration}} \propto \mathrm{T}^{0} \\ \mathrm{q}_{\text{rotation}} \propto \mathrm{T}\,(\text{linear molecule}) & \mathrm{q}_{\text{rotation}} \propto \mathrm{T}^{3/2}\,(\text{non-linear molecule}) \end{array} \]
According to the Conventional Transition State Theory (CTST), the temperature dependence of the Arrhenius pre-exponential factor for a reaction of the type given below is linear molecule + linear molecule $\rightleftharpoons$ non-liner linear transition state $\rightarrow$ products. (a) $\mathrm{T}^{-1}$
(b) $\mathrm{T}^{0}$
(c) $\mathrm{T}^{1}$
(d) $\mathrm{T}^{2}$
Answer Explanation No explanation was printed for this question.
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