Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Rate Laws Order · Exam: JAM 2001-2022 · Marks: 2 · Difficulty: Hard
The rate constant k for a second order reaction $\mathrm{P + Q \rightarrow}$ Products is expressed $\log_{10}\mathrm{k} = 20 - \dfrac{3000}{\mathrm{T}}$, where the concentration is in $\mathrm{mol\,lit^{-1}}$, T is in absolute temperature and time is in minutes. The initial concentrations of both the reactants are 0.05 M. Calculate the activation energy and half life of the reaction at $27^{\circ}\mathrm{C}$. ($\mathrm{R = 2\,cal\,K^{-1}\,mol^{-1}}$)
Answer
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