ABC26PH0936 · Chemical Kinetics

Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Steady State Approximation · Exam: NET DEC 2016 · Marks: 2 · Difficulty: Medium

A reaction goes through the following elementary steps
\[ \begin{array}{l} \mathrm{A}+\mathrm{B} \xrightarrow[\mathrm{k}_{-1}]{\mathrm{k}_{1}} 2 \mathrm{C} \text { (fast) } \\ \mathrm{A}+\mathrm{C} \xrightarrow{\mathrm{k}_{2}} \mathrm{D} \text { (slow) } \end{array} \]
Assuming that steady state approximation can be applied to C, on doubling the concentration of A, the rate of production of D will increase by (assume $\mathrm{K}_{2}[\mathrm{A}] \ll \mathrm{K}_{-1}[\mathrm{C}]$ )
(a)2 times
(b)4 times
(c)8 times
(d)$2 \sqrt{2}$ times
Answer
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Explanation
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