Elementary steps of a reaction are as follows arrayl A+B [k-1]k1 2 C \\ 2 C k2 D array If steady state approximation is applicable to C, the rate of product formation in the reaction is

ABC26PH0947 · Chemical Kinetics

Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Steady State Approximation · Exam: NET JUNE 2018 · Marks: 2 · Difficulty: Hard

Elementary steps of a reaction are as follows

\[ \begin{array}{l} \mathrm{A}+\mathrm{B} \xrightarrow[\mathrm{k}_{-1}]{\mathrm{k}_{1}} 2 \mathrm{C} \\ 2 \mathrm{C} \xrightarrow{\mathrm{k}_{2}} \mathrm{D} \end{array} \]

If steady state approximation is applicable to C, the rate of product formation in the reaction is

(a)proportional to [A][B]

(b)proportional to $[\mathrm{A}]^{2}[\mathrm{B}]^{2}$

(c)proportional to $[\mathrm{A}]^{1 / 2}[\mathrm{B}]^{1 / 2}$

(d)independent of $[\mathrm{A}][\mathrm{B}]$

Answer

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Explanation

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