ABC26PH1143 · Molecular Spectroscopy

Subject: Physical Chemistry · Chapter: Molecular Spectroscopy · Topic: Vibrational · Exam: NET JUNE 2019 · Marks: 2 · Difficulty: Medium

The Berge-Sponer plot between $\Delta \mathrm{G}_{\mathrm{v}+\frac{1}{2}}=\left(\varepsilon_{\mathrm{v}+1}-\varepsilon_{\mathrm{v}}\right)$ and $v+1$ for CO in a straight line with slope of $-14 \mathrm{cm}^{-1}$ and intercept of $2170 \mathrm{cm}^{-1}$. The approximate value of dissociation energy of CO (in $c m^{-1}$ ) is (Assume CO as an Anharmonic oscillator with energy expression.
\[ \varepsilon_{v}=\left(v+\frac{1}{2}\right) \omega-\left(v+\frac{1}{2}\right)^{2} x_{e} \omega ; D=\frac{\omega}{4 x_{e}} \]
(a)42044
(b)84088
(c)168175
(d)336350
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