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Crystal Lab › Elements & packing

Graphite C

Covalent layers · space group P6₃/mmc (No. 194) · Z = 4

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Unit cell

Lattice constants
a = 2.464 Å, b = 2.464 Å, c = 6.711 Å; α = 90°, β = 90°, γ = 120°
Cell volume
35.3 ų
Atoms in the cell
4 (C 4)
Formula units Z
4
Calculated density
2.26 g cm⁻³
Shortest contact
1.423 Å

Coordination

C
CN 3 at 1.42 Å (3 C)

About the structure

  • Flat hexagonal layers (C–C 1.42 Å) stacked ABAB, 3.35 Å apart.
  • Three σ bonds per carbon in the layer; the fourth electron is delocalised, hence the conductivity.
  • Layers are held only by dispersion forces, so they slide: the lubricant and the pencil.

Atom positions (fractional, one cell)

Atomxyz
C0.00000.00000.2500
C0.00000.00000.7500
C0.33330.66670.2500
C0.66670.33330.7500

Z, coordination numbers, distances, density and packing on this page are computed from these coordinates.

Other elements & packing

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