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Symmetry Lab › D2d › Spiropentane

C₅H₈ Spiropentane

Two perpendicular three-membered rings sharing one carbon · point group D2d · order 8

Open C₅H₈ in 3D →

Point group
D2d — A C2 principal axis, 2 perpendicular C2 axes and 2 dihedral mirror planes that bisect them; the principal axis is also an S4 axis.
Order
8
Operations
E, 2S₄, C₂, 2C₂′, 2σd
Shape
Two perpendicular three-membered rings sharing one carbon
Atoms
13 (C × 5, H × 8)

Symmetry elements of C₅H₈

  • C₂ — through the spiro carbon, along both ring bisectors
  • S₄ — rotate 90°, then reflect: swaps the two rings
  • C₂′ (1) — through the spiro carbon, between the ring planes
  • C₂′ (2) — through the spiro carbon, between the ring planes
  • σd (1) — the plane of one ring
  • σd (2) — the plane of the other ring

Structure

  • C–C 1.48–1.52 Å
  • The two rings lie in perpendicular planes
  • Same point group as allene
Spiropentane (C5H8) — D2d symmetry elements
Spiropentane: symmetry elements of the D2d point group

Other D2d molecules

Open in the 3D lab →  ·  All D2d molecules  ·  All point groups