ABC26IN0234 · Organometallic Compounds

Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Organometallic Compounds – General · Exam: CSIR-NET DEC 2012 · Marks: 2 · Difficulty: Medium

Consider the catalyst in column-I and reaction in column-II Column-I Column-II A [(R)-BINAP] $\mathrm{Ru}^{-2}$ i. Hydroformylation.
(b)$\left[\mathrm{Rh}(\mathrm{CO})_{\mathrm{2}} \mathrm{I}_{\mathrm{2}}\right]^{-\mathrm{1}}$ ii. asymmetric hydrogenation (A-i), (B-ii), (C-iii), (D-iv)
(c)$\left[\mathrm{Pd}\left(\mathrm{PPh}_{\mathrm{3}}\right)_{\mathrm{4}}\right]$ iii. Asymmetric hydrogen transfer D iv heck coupling The best match of a catalyst of column-I with the reaction nuclear column-II is (A-iii), (B-i), (C-iv), (D-ii)
(a)(A-ii), (B-i), (C-iv), (D-iii)
(d)(A-iv), (B-iii), (C-ii), (D-i)
Answer
Answer (as printed): B
Explanation
$[\mathrm{Rh(CO)_2I_2}]^{-} \rightarrow$ Hydroformylation. $[\mathrm{Pd(PPh_3)_4}] \rightarrow$ Heck coupling (it is a catalyst for Heck coupling).

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