For the following reaction, A k-1k1 2\,B \ ; B k2 C (d[B])/dt is given by

ABC26PH0038 · Chemical Kinetics

Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Chemical Kinetics – General · Exam: CSIR-NET DEC 2015 · Marks: 2 · Difficulty: Easy

For the following reaction,

\[ \mathrm{A} \underset{k_{-1}}{\overset{k_{1}}{\rightleftharpoons}} 2\,\mathrm{B} \ ; \quad \mathrm{B} \xrightarrow{k_{2}} \mathrm{C} \]

$\dfrac{d[B]}{dt}$ is given by

(a)$k_{1}[A]-k_{-1}[B]^{2}-2k_{2}[B]$

(b)$2k_{1}[A]-k_{-1}[B]^{2}-k_{2}[B]$

(c)$\dfrac{1}{2}k_{1}[A]-\dfrac{1}{2}k_{-1}[B]^{2}-k_{2}[B]$

(d)$2k_{1}[A]-2k_{-1}[B]^{1/2}-k_{2}[B]$

Answer

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Explanation

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