ABC26PH0977 · Electrochemistry
Subject: Physical Chemistry · Chapter: Electrochemistry · Topic: Nernst Cells · Exam: NET JUNE 2012 · Marks: 2 · Difficulty: Medium
The correct Nernst equation for the concentration cell: \[ \mathrm{Pt}\left|\mathrm{H}_{2}(\mathrm{p})\right| \mathrm{HCl}\left(a_{ \pm}\right)_{1}|\mathrm{AgCl}(\mathrm{s})| \mathrm{Ag} \| \mathrm{Ag}|\mathrm{AgCl}(\mathrm{s})| \mathrm{HCl}\left(a_{ \pm}\right)_{2}|\mathrm{H}(\mathrm{p})| \mathrm{Pt} \]
without liquid junction would be (a)$\mathrm{E}=\frac{2 R T}{F} \ln \frac{\left(a_{ \pm}\right) 1}{\left(a_{ \pm}\right) 2}$
(b)$\mathrm{E}=\frac{2 R T}{F} \ln \frac{\left(a_{ \pm}\right) 2}{\left(a_{ \pm}\right) 1}$
(c)$\mathrm{E}=\frac{R T}{F} \ln \frac{\left(a_{ \pm}\right) 2}{\left(a_{ \pm}\right) 1}$
(d)$\mathrm{E}=\frac{R T}{2 F} \ln \frac{\left(a_{ \pm}\right) 2}{\left(a_{ \pm}\right) 1}$
Answer
Explanation
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