The standard reduction potentials at 298 K for single electrodes are given below: From this we can infer that · ABC26PH0394

Subject: Physical Chemistry · Chapter: Electrochemistry · Topic: Nernst Cells · Exam: GATE 2005-2021 · Marks: 2 · Difficulty: Medium

The standard reduction potentials at 298 K for single electrodes are given below:
ElectrodeElectrode Potential (volt)
$\mathrm{Mg}^{2+}/\mathrm{Mg}$-2.34
$\mathrm{Zn}^{2+}/\mathrm{Zn}$-0.76
$\mathrm{Zn}^{2+}/\mathrm{Fe}$-0.44
From this we can infer that
(a)Zn can reduce both $\mathrm{Mg}^{2+}$ and $\mathrm{Fe}^{2+}$
(b)Fe can reduce both $\mathrm{Mg}^{2+}$ and $\mathrm{Zn}^{2+}$
(c)Mg can reduce both $\mathrm{Zn}^{2+}$ and $\mathrm{Fe}^{2+}$
(d)Mg can reduce $\mathrm{Zn}^{2+}$ but not $\mathrm{Fe}^{2+}$
Answer
Answer: C ✓ checked by 4AB · confidence high

The source book printed no answer; this one was worked out and checked — see the explanation.

Explanation
The most negative couple (Mg²⁺/Mg, −2.34 V) is the strongest reducing agent, so Mg reduces both Zn²⁺ (−0.76 V) and Fe²⁺ (−0.44 V); Zn cannot reduce Mg²⁺ (c).

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