Subject: Physical Chemistry · Chapter: Molecular Spectroscopy · Topic: Vibrational · Exam: NET JUNE 2012 · Marks: 2 · Difficulty: Medium
The following data were obtained from the vibrational fine structure in the vibronic spectrum of a diatomic molecule: $\omega_{\mathrm{e}}=512 \mathrm{cm}^{-1}, \omega_{\mathrm{e}} \mathrm{x}_{\mathrm{e}}=8 \mathrm{cm}^{-1}$ where $\omega_{\mathrm{e}}$ is the energy associated with the natural frequency of vibration and xe is the anharmonicity constant. The dissociation energy (De) of the molecule is: