CSIR-NET December 2013 · chemistry questions

120 questions from this paper that are in the bank. Each opens with its answer and explanation.

ABC26IN0004 · Among the following, the correct acid strength trend is represented by · Acid and Bases – General
ABC26IN0005 · Water plays different roles in the following reactions. arrayl (i) 2H2O + Ca Ca2+ + 2OH^- + H2 \\ (ii) nH2O + Cl [Cl(H2O)n]- \\ (iii) 6H2O… · Acid and Bases – General
ABC26IN0031 · In the atomic absorption spectroscopic estimation of Fe(III) using O2 / H2 flame, the absorbance decreases with the addition of: · Analytical Chemistry – General
ABC26IN0062 · Among the following, an example of a hypervalent species is · Chemical Bonding – General
ABC26IN0063 · The energy of 2 s and 2 p orbitals is the same for · Chemical Bonding – General
ABC26OR0022 · Amongst the following, the compound which has the lowest energy barrier for the cis-trans isomerisation is: · General Organic Chemistry – General
ABC26OR0023 · The IUPAC name of the compound given below is · Nomenclature Polycyclics
ABC26OR0024 · The two benzylic hydrogens HA and HB in the compounds I and II, are (I) (II) · General Organic Chemistry – General
ABC26OR0025 · (being typed) · Acidity Basicity
ABC26OR0026 · The absolute configuration of the two stereogenic (chiral) centres in the following molecule is · Stereochemistry R S E Z
ABC26OR0027 · The correct statement about the following molecule is · Stereochemistry R S E Z
ABC26OR0028 · Consider the following statements about cis- and trans-decalins · General Organic Chemistry – General
ABC26OR0029 · The correct order for the rates of electrophilic aromatic substitution of the following compound is (I) (II) (III) · Aromaticity
ABC26OR0092 · For estrone, among the statements A-C, the correct ones are · Steroids
ABC26OR0093 · The constituent amino acids present in the following dipeptide, respectively, are · Amino Acids Peptides
ABC26OR0094 · The major product B formed in the following reaction sequence, and overall yield of its formation are A B · Natural Products – General
ABC26OR0095 · The major product formed in the sulfuric acid mediated rearrangement of the sesquiterpene saritonin A is · Terpenoids
ABC26OR0096 · The peptide A on reaction with 1-fluoro-2, 4-dinitrobenzene followed by exhaustive hydrolysis gave phenylalanine, alanine, serine and N-(2… · Amino Acids Peptides
ABC26OR0127 · In the IR spectrum of p-nitrophenyl acetate, the carbonyl absorption band appears at · IR
ABC26OR0146 · The following reaction proceeds through a Delta · Sigmatropic Shifts
ABC26OR0147 · The number of nodes present in the highest occupied molecular orbital of 1, 3, 5-hexatriene in its ground state is · Pericyclic Reactions – General
ABC26OR0148 · (being typed) · Pericyclic Reactions – General
ABC26OR0162 · The major product formed in the following photochemical reaction is · Photocycloaddition
ABC26OR0220 · The major product formed in the following reaction is: · Named Reactions
ABC26OR0221 · The major product formed in the following reaction is: · Named Reactions
ABC26OR0222 · The major product formed in the following reaction is: · Named Reactions
ABC26OR0224 · The major product formed in the following reaction sequence is: · Reagents, Reaction Mechanisms & Named Reactions – General
ABC26OR0225 · In the following transformation, the reagent A and the major product B , respectively, are and · Reagents, Reaction Mechanisms & Named Reactions – General
ABC26OR0226 · The major product formed in the following reaction sequence is: 1. BH3, THF ; H2 O2 / NaOH 2. Ph3 P, DEAD, 4-nitrobenzoic acid 3. K2 CO3… · Reagents, Reaction Mechanisms & Named Reactions – General
ABC26OR0227 · The major product formed in the following reaction sequence is: · Reagents, Reaction Mechanisms & Named Reactions – General
ABC26OR0228 · The major product formed in the following reaction sequence is: · Reagents, Reaction Mechanisms & Named Reactions – General
ABC26OR0229 · The major product formed in the following reaction sequence is: · Reduction Reagents
ABC26PH0026 · According to Arrhenius equation ( k= rate constant and T= temperature) · Rate Laws Order
ABC26PH0027 · A first order gaseous reaction is 25\% complete in 30 minutes at 227 and in 10 minutes at 237. The activation energy of the reaction is… · Arrhenius Activation
ABC26PH0028 · In the reaction between NO and H2 the following data are obtained Experiment I: PH2 constant Experiment II : PNO = constant The orders with… · Chemical Kinetics – General
ABC26PH0029 · For a first order reaction A products, the plot of (([A]t)/([A]0) ) vs time, where [A]0 and [A]t to cocentration at time =0 and t… · Rate Laws Order
ABC26PH0058 · The limiting molar conductivities of NaCl, NaI and RbI are 12.7, 10.8 and 9.1\,mS\,m2\,mol-1, respectively. The limiting molar conductivity… · Conductance
ABC26PH0201 · The number of ways in which four molecules can be distributed in two different energy levels is : · Statistical Thermodynamics – General
ABC26PH0232 · The chemical potential ( ) of the i^ th component is defined as · Partial Molar Quantities
ABC26PH0233 · Work (w) involved in isothermal reversible expansion from Vi to Vf of n moles of an ideal gas is · Thermodynamics – General
ABC26IN0804 · Among the following, the correct acid strength trend is represented by · Acids & Bases – General
ABC26IN0848 · In the atomic absorption spectroscopic estimation of Fe(III) using O2 / H2 flame, the absorbance decreases with the addition of · Analytical Chemistry – General
ABC26IN0866 · Patients suffering from Wilson's disease have · Copper Proteins
ABC26IN0867 · High dose of dietary supplement ZnSO4, for the cure of Zn deficiency · Copper Proteins
ABC26IN0868 · L-DOPA is used for treatment of · Bioinorganic Chemistry – General
ABC26IN0869 · Oxidised form of enzyme catalase (structure A ); prepared by the reaction of [Fe(P)]+(P= porphyrin ) with H2 O2 has green color because · Iron Sulfur Proteins
ABC26IN1031 · An octahedral metal ion M2+ has magnetic moment of 4.0 B.M. The correct combination of metal ion and d-electron configuration is given by · Electron Transfer Redox
ABC26IN1032 · For an electronic configuration of two non-equivalent pi electronics [ pi 1, pi 1 ] which of the Following terms is not possible? · Electron Transfer Redox
ABC26IN1033 · Among the following, the correct combination of complex and its color is · Coordination Chemistry – General
ABC26IN1034 · MnCr2 O4 is likely to have a normal spinel structure because · Coordination Chemistry – General