ABC26OR0127 · Organic Spectroscopy

Subject: Organic Chemistry · Chapter: Organic Spectroscopy · Topic: IR · Exam: CSIR-NET DEC 2013 · Marks: 2 · Difficulty: Easy

In the IR spectrum of p-nitrophenyl acetate, the carbonyl absorption band appears at
(a)$1660\,\mathrm{cm}^{-1}$
(b)$1700\,\mathrm{cm}^{-1}$
(c)$1730\,\mathrm{cm}^{-1}$
(d)$1770 \mathrm{cm}^{-1}$
Answer
Answer (as printed): D
Explanation
The carbonyl ester peaks appears at a higher frequency than for a normal ester because of the presence of strong electron withdrawing p-nitrophenoxy group.

Explanation as extracted from the printed page; notation may be imperfect.

Open in whiteboard · Browse this chapter in the app