Unit cell
- Lattice constants
- a = 4.240 Å, b = 4.240 Å, c = 6.840 Å; α = 90°, β = 90°, γ = 120°
- Cell volume
- 106.5 ų
- Atoms in the cell
- 3 (Cd 1, I 2)
- Formula units Z
- 1
- Calculated density
- 5.71 g cm⁻³
- Shortest contact
- 2.986 Å
Coordination
- Cd
- CN 6 at 2.99 Å (6 I)
- I
- CN 3 at 2.99 Å (3 Cd)
About the structure
- hcp array of I⁻ with Cd²⁺ in every other layer of octahedral holes.
- Layers I–Cd–I are neutral sandwiches held together only by dispersion forces.
- Mg(OH)₂ (brucite), Ca(OH)₂, PbI₂, TiS₂, VS₂ share this structure.
Atom positions (fractional, one cell)
| Atom | x | y | z |
|---|---|---|---|
| Cd | 0.0000 | 0.0000 | 0.0000 |
| I | 0.3333 | 0.6667 | 0.2500 |
| I | 0.6667 | 0.3333 | 0.7500 |
Z, coordination numbers, distances, density and packing on this page are computed from these coordinates.