Q76 · CSIR-NET Chemistry, December 2011

Paper: CSIR-NET December 2011 · Subject: Organic Chemistry · Chapter: Pericyclic Reactions · Topic: Electrocyclic · Marks: 2 · Difficulty: Medium

In the following concerted reaction, the product is formed by a Question structure 1 of 2, ABC26OR1017 $\xrightarrow{\Delta}$ Question structure 2 of 2, ABC26OR1017
(a)$6 \pi$ - disrotatory electrocyclisation
(b)$4 \pi$ - disrotatory electrocyclisation
(c)$6 \pi$ - conrotatory electrocyclisation
(d)$4 \pi$ - conrotatory electrocyclisation
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
Cyclooctatetraene closes to cis-bicyclo[4.2.0]octatriene by a thermal 6π (4n+2) disrotatory electrocyclisation (a).

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