Q67 · CSIR-NET Chemistry, December 2012

Paper: CSIR-NET December 2012 · Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Cluster Compounds Wade Rules · Marks: 2 · Difficulty: Medium

In the cluster $\left[\mathrm{Co}_{3}(\mathrm{CH})(\mathrm{CO})_{9}\right]$ obeying 18e rule, the number of metal-metal bonds and the bridging ligands respectively, are
(a)3 and 1 CH
(b)0 and 3 CO
(c)3 and 1 CO
(d)6 and 1 CH
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
[Co₃(μ₃-CH)(CO)₉] has a Co₃ triangle (3 Co–Co bonds) capped by one μ₃-CH; all nine CO are terminal. Each Co reaches 18 e (a).

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