Q8 · CSIR-NET Chemistry, December 2012
Paper: CSIR-NET December 2012 · Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Oxidative Addition Reductive Elimination · Marks: 2 · Difficulty: Medium
Reactions A and B are, termed as respectively. (A) 
+ 
$\longrightarrow$ 
(B) 
+ 
+ 
+ $\longrightarrow$ (B) + + (a)Insertion, Metathesis
(b)Metathesis, insertion
(c)Oxidative, addition, metathesis
(d)Oxidative addition, insertion
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
(A) SnCl₂ inserts into the Co–Co bond of Co₂(CO)₈ to give Cl₂Sn[Co(CO)₄]₂ (insertion). (B) Me₂SnCl₂ + 2Na[Re(CO)₅] → Me₂Sn[Re(CO)₅]₂ + 2NaCl is salt metathesis (a).
Study loop for Organometallic Compounds