Q56 · CSIR-NET Chemistry, December 2013

Paper: CSIR-NET December 2013 · Subject: Inorganic Chemistry · Chapter: Main Group Elements · Topic: Main Group Elements – General · Marks: 2 · Difficulty: Easy

The reaction of $\mathrm{FeCl}_{3} \cdot 6 \mathrm{H}_{2} \mathrm{O}$ with $\mathrm{SOCl}_{2}$ yields.
(a)$\mathrm{FeCl_2(s)}, \mathrm{SO_2(g)}$ and $\mathrm{HCl(g)}$
(b)$\mathrm{FeCl_3(s)}, \mathrm{SO_2(g)}$ and $\mathrm{HCl(l)}$
(c)$\mathrm{FeCl_2(S)}, \mathrm{SO_2(s)}$ and $\mathrm{HCl(g)}$
(d)$\mathrm{FeCl_3(s)}, \mathrm{SO_2(g)}$ and $\mathrm{HCl(g)}$
Answer
Answer: D ✓ checked by 4AB · confidence high
Explanation
SOCl₂ is the standard dehydrating agent for hydrated chlorides: FeCl₃·6H₂O + 6SOCl₂ → FeCl₃ + 6SO₂(g) + 12HCl(g), giving anhydrous FeCl₃ without hydrolysis.

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