Q107 · CSIR-NET Chemistry, December 2014

Paper: CSIR-NET December 2014 · Subject: Physical Chemistry · Chapter: Surface Chemistry · Topic: Surface Chemistry – General · Marks: 2 · Difficulty: Medium

Hydrogen is adsorbed on many metal surfaces by dissociation (S represents a surface site)- Question structure 1 of 2, ABC26PH1426 Question structure 2 of 2, ABC26PH1426 If the pressure of $\mathrm{H}_{2}(\mathrm{p})$ is small, the fraction of the surface covered by hydrogen is proportional to
(a)p
(b)$\mathrm{p}^{2}$
(c)$p^{1 / 2}$
(d)$p^{1 / 2}$
Answer
Answer: C ✓ checked by 4AB · confidence high
Explanation
Dissociative Langmuir: θ = (Kp)^½/[1 + (Kp)^½] ≈ (Kp)^½ at low pressure.

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