Q22 · CSIR-NET Chemistry, December 2014

Paper: CSIR-NET December 2014 · Subject: Organic Chemistry · Chapter: Reagents, Reaction Mechanisms & Named Reactions · Topic: Named Reactions · Marks: 2 · Difficulty: Medium

The major product of the following reaction is: Question structure 1 of 4, ABC26OR0252 Question structure 2 of 4, ABC26OR0252 Question structure 3 of 4, ABC26OR0252 Question structure 4 of 4, ABC26OR0252
(a)Option (a) structure, ABC26OR0252
(b)Option (b) structure, ABC26OR0252
(c)Option (c) structure, ABC26OR0252
(d)Option (d) structure, ABC26OR0252
Answer
Answer: D ✓ checked by 4AB · confidence medium
Explanation
Sarcosine condenses with the aldehyde and decarboxylates, forming an azomethine ylide. Intramolecular [3+2] cycloaddition onto the N-allyl alkene gives the cis-fused pyrrolo[3,2-c]quinoline (d).

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