Q60 · CSIR-NET Chemistry, December 2014

Paper: CSIR-NET December 2014 · Subject: Inorganic Chemistry · Chapter: Main Group Elements · Topic: Main Group Elements – General · Marks: 2 · Difficulty: Medium

Among $\mathrm{F^{-}}$, $\mathrm{Na^{+}}$, $\mathrm{O^{2-}}$ and $\mathrm{Mg^{2+}}$ ions, those having the highest and the lowest ionic radii respectively are
(a)$\mathrm{O}^{2-}$ and $\mathrm{Na}^{+}$
(b)$\mathrm{F}^{-}$and $\mathrm{Mg}^{2+}$
(c)$\mathrm{O}^{2-}$ and $\mathrm{Mg}^{2+}$
(d)$\mathrm{Mg}^{2+}$ and $\mathrm{O}^{2-}$
Answer
Answer: C ✓ checked by 4AB · confidence high
Explanation
All four are isoelectronic (10 e); size falls with nuclear charge: O²⁻ (140 pm) > F⁻ > Na⁺ > Mg²⁺ (72 pm).

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