Q33 · CSIR-NET Chemistry, December 2015

Paper: CSIR-NET December 2015 · Subject: Physical Chemistry · Chapter: Statistical Thermodynamics · Topic: Maxwell Boltzmann · Marks: 2 · Difficulty: Easy

The standard deviation of speed $\left(\sigma_{c}\right)$ for Maxwell's distribution satisfies the relation
(a)$\sigma_{c} \propto T$
(b)$\sigma_{c} \propto \sqrt{T}$
(c)$\sigma_{c} \propto \frac{1}{T}$
(d)$\sigma_{c} \propto 1/\sqrt{T}$
Answer
Answer: B ✓ checked by 4AB · confidence medium
Explanation
σ_c = √(3 − 8/π)·√(RT/M), so the standard deviation of speed is proportional to √T.

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