Q8 · CSIR-NET Chemistry, December 2015

Paper: CSIR-NET December 2015 · Subject: Organic Chemistry · Chapter: Reagents, Reaction Mechanisms & Named Reactions · Topic: Reagents, Reaction Mechanisms & Named Reactions – General · Marks: 2 · Difficulty: Medium

The major product formed in the following reaction sequence is: Question structure, ABC26OR0266
(a)Option (a) structure, ABC26OR0266
(b)Option (b) structure, ABC26OR0266
(c)Option (c) structure, ABC26OR0266
(d)Option (d) structure, ABC26OR0266
Answer
Answer: D ✓ checked by 4AB · confidence high
Explanation
Conrad–Limpach: the enamine diester cyclises thermally (Ph₂O reflux) onto the ring to give the 4-quinolone bearing the 2-ester; CF₃ and Cl are retained (d).

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