Q22 · CSIR-NET Chemistry, December 2016

Paper: CSIR-NET December 2016 · Subject: Physical Chemistry · Chapter: Atomic and Molecular Term Symbol · Topic: Molecular Term Symbols · Marks: 2 · Difficulty: Medium

The highest molecular orbitals for an excited electronic configuration of the oxygen molecule are $\left[1 \pi_{g}\right]^{1}\left[3 \sigma_{u}\right]^{1}$. A possible molecular term symbol for oxygen with this electronic configuration is
(a)${ }^{1} \Pi$
(b)${ }^{3} \Sigma$
(c)${ }^{1} \Delta$
(d)${ }^{1} \Sigma$
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
πg¹σu¹ gives Λ = 1, a Π state (singlet or triplet): ¹Π (a).

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