Q63 · CSIR-NET Chemistry, December 2016

Paper: CSIR-NET December 2016 · Subject: Inorganic Chemistry · Chapter: Organometallic Compounds · Topic: Metal Alkene Alkyne · Marks: 2 · Difficulty: Easy

The rate of alkene coordination to $\left[\mathrm{PtCl}_{4}\right]^{2-}$ is highest for
(a)norbornene
(b)ethylene
(c)cyclohexene
(d)1-butene
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
Strained alkenes coordinate fastest: norbornene's ring strain is relieved on binding, so it displaces chloride from [PtCl₄]²⁻ much faster than ethylene, 1-butene or cyclohexene.

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