Q30 · CSIR-NET Chemistry, December 2018

Paper: CSIR-NET December 2018 · Subject: Inorganic Chemistry · Chapter: Coordination Chemistry · Topic: Coordination Chemistry – General · Marks: 2 · Difficulty: Medium

Consider the species $\mathrm{NO}, \mathrm{I}_{2}, \mathrm{I}_{2}^{-}, \mathrm{Cu}^{2+}$ and $\mathrm{VO}^{2+}$. The number of paramagnetic species among them and the EPR inactive species, respectively, are
(a)4 and $\mathrm{I}_{2}^{-}$
(b)4 and $\mathrm{I}_{2}$
(c)3 and $\mathrm{VO}^{2+}, \mathrm{Cu}^{2+}$
(d)3 and $\mathrm{NO}, \mathrm{Cu}^{2+}$
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
Paramagnetic: NO, I₂⁻, Cu²⁺ (d⁹), VO²⁺ (d¹) — four; I₂ is diamagnetic and hence EPR-inactive.

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