Q32 · CSIR-NET Chemistry, December 2019

Paper: CSIR-NET December 2019 · Subject: Organic Chemistry · Chapter: Reagents, Reaction Mechanisms & Named Reactions · Topic: Reagents, Reaction Mechanisms & Named Reactions – General · Marks: 2 · Difficulty: Medium

The major product in the following reaction sequence is Question structure 1 of 2, ABC26OR0441 Question structure 2 of 2, ABC26OR0441
(a)Option (a) structure, ABC26OR0441
(b)Option (b) structure, ABC26OR0441
(c)Option (c) structure, ABC26OR0441
(d)Option (d) structure, ABC26OR0441
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
The OMOM group directs t-BuLi lithiation to C-4 of 3-(methoxymethoxy)pyridine. 1,2-Diiodoethane acts as an I⁺ source (releasing ethylene), giving 4-iodo-3-(MOM-oxy)pyridine (b).

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