Q150 · CSIR-NET Chemistry, June 2011

Paper: CSIR-NET June 2011 · Subject: Physical Chemistry · Chapter: Thermodynamics · Topic: Free Energy Equilibria · Marks: 2 · Difficulty: Medium

A process is carried out at constant volume and at constant entropy. It will be spontaneous if:
(a)$\Delta \mathrm{G}<0$
(b)$\Delta \mathrm{H}<0$
(c)$\Delta \mathrm{U}<0$
(d)$\Delta \mathrm{A}<0$
Answer
Answer: C ✓ checked by 4AB · confidence high
Explanation
At constant S and V the criterion for spontaneity is dU < 0 (c).

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