Q41 · CSIR-NET Chemistry, June 2011

Paper: CSIR-NET June 2011 · Subject: Physical Chemistry · Chapter: Quantum Chemistry · Topic: Hydrogen Atom · Marks: 2 · Difficulty: Medium

Under review — part of this question (a structure or an option) is not clear in the source scan. 4AB is checking it against the original book; the answer shown may change.
$\begin{array}{l}1.1 2.2 3.3 4.4\end{array}$
(a)Greater than – 0.5 au
(b)Equal to – 0.5 au
(c)Less than – 0.5 au
(d)Equal to ζ times – 0.5 au.
Answer
Under review — not yet confirmed.
Answer: A

The source book printed C; on checking, A is correct — see the explanation.

Book printed (c).

Explanation
By the variation theorem any trial function other than the exact one (ζ = 1) gives ⟨E⟩ = ζ²/2 − ζ > −0.5 au — greater than −0.5 au (a).

Study loop for Quantum Chemistry

1. Practise the PYQsPrevious-year questions, with answers

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