Q7 · CSIR-NET Chemistry, June 2012

Paper: CSIR-NET June 2012 · Subject: Organic Chemistry · Chapter: General Organic Chemistry · Topic: Stereochemistry R S E Z · Marks: 2 · Difficulty: Medium

Epoxidation of (R)-cyclohex-2-enol with peracetic acid yields a 95:5 mixture of compounds A and B. Compounds A and B are
(a)Enantiomers
(b)Diastereomers
(c)Constitutional isomers
(d)Homomers
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
Epoxidation on the two faces of the chiral alkene gives the syn (OH-directed, major) and anti epoxides: same connectivity, different relative configuration — diastereomers.

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