Q24 · CSIR-NET Chemistry, June 2013

Paper: CSIR-NET June 2013 · Subject: Physical Chemistry · Chapter: Surface Chemistry · Topic: Surface Tension · Marks: 2 · Difficulty: Medium

"Colloids are thermodynamically unstable with reference to bulk but kinetically stable". Identify the correct pair
StatementsReasons
(A) thermodynamically unstable(C) interfacial surface tension
(B) kinetically stable(D) electrical double layer
(a)(A) $\leftrightarrow$ (D) and (B) $\leftrightarrow$ (C)
(c)(A) $\leftrightarrow$ (C) and (B) $\leftrightarrow$ (C)
(b)(A) $\leftrightarrow$ (C) and (B) $\leftrightarrow$ (D)
(d)(A) $\leftrightarrow$ (D) and (B) $\leftrightarrow$ (D)
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
The large interfacial (surface) free energy makes colloids thermodynamically unstable, and the electrical double layer repulsion keeps them kinetically stable: A ↔ C, B ↔ D.

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