Q34 · CSIR-NET Chemistry, June 2014

Paper: CSIR-NET June 2014 · Subject: Inorganic Chemistry · Chapter: Inorganic Spectroscopy · Topic: Inorganic Spectroscopy – General · Marks: 2 · Difficulty: Easy

The $^{19}\mathrm{F}$ NMR spectrum of $\mathrm{ClF}_{3}$ shows
(a)doublet and triplet for a T-shaped structure
(b)singlet for a trigonal planar structure
(c)singlet for a trigonal pyramidal structure
(d)doublet and singlet for a T-shaped structure
Answer
Answer: A ✓ checked by 4AB · confidence high
Explanation
T-shaped ClF₃ has two equivalent axial F (doublet) and one equatorial F (triplet).

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