Q59 · CSIR-NET Chemistry, June 2014

Paper: CSIR-NET June 2014 · Subject: Organic Chemistry · Chapter: Pericyclic Reactions · Topic: Pericyclic Reactions – General · Marks: 2 · Difficulty: Medium

The major product formed in the following reaction is Question structure, ABC26OR1035 $\xrightarrow{\Delta}$
(a)Option (a) structure, ABC26OR1035
(b)Option (b) structure, ABC26OR1035
(c)Option (c) structure, ABC26OR1035
(d)Option (d) structure, ABC26OR1035
Answer
Answer: B ✓ checked by 4AB · confidence medium
Explanation
Thermal conrotatory opening of the cis-aziridine gives the azomethine ylide. [3+2] cycloaddition with diphenylacetylene gives the 3-pyrroline with the two ester groups trans (b).

Study loop for Pericyclic Reactions

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