Q62 · CSIR-NET Chemistry, June 2014

Paper: CSIR-NET June 2014 · Subject: Physical Chemistry · Chapter: Chemical Kinetics · Topic: Rate Laws Order · Marks: 2 · Difficulty: Medium

Examine the following first order consecutive reactions. The rate constant (in $\mathrm{s}^{-1}$ units) for each step is given above the arrow mark
(A) $\mathrm{P} \xrightarrow{10^{5}} \mathrm{Q} \xrightarrow{10^{3}} \mathrm{R}$(B) $\mathrm{P} \xrightarrow{10^{5}} \mathrm{Q} \xrightarrow{10^{3}} \mathrm{R}$
(C) $\mathrm{P} \xrightarrow{10^{7}} \mathrm{Q} \xrightarrow{10^{7}} \mathrm{R}$(D) $\mathrm{P} \xrightarrow{10^{2}} \mathrm{Q} \xrightarrow{10^{5}} \mathrm{R}$
Steady-state approximation can be applied to
(a)A only
(b)C only
(c)B and C only
(d)A and D only
Answer
SELF-PRACTICE — the source book printed no answer.

Nothing is invented here, so this question has no answer on record.

Explanation
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