Q88 · CSIR-NET Chemistry, June 2014

Paper: CSIR-NET June 2014 · Subject: Physical Chemistry · Chapter: Quantum Chemistry · Topic: Quantum Chemistry – General · Marks: 2 · Difficulty: Hard

A quantum particle with fixed initial energy $E_{0}<V$ is allowed to strike the following four barriers separately. The transmission probability is maximum in
(a)Option (a) structure, ABC26PH1261
(b)Option (b) structure, ABC26PH1261
(c)Option (c) structure, ABC26PH1261
(d)Option (d) structure, ABC26PH1261
Answer
Answer: B ✓ checked by 4AB · confidence high

The source book printed no answer; this one was worked out and checked — see the explanation.

Explanation
T ≈ exp[−2a√(2m(V−E))/ħ], so the thinnest and lowest barrier, width A and height V, transmits most (b).

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