Q6 · CSIR-NET Chemistry, June 2015

Paper: CSIR-NET June 2015 · Subject: Organic Chemistry · Chapter: General Organic Chemistry · Topic: General Organic Chemistry – General · Marks: 2 · Difficulty: Hard

The correct order of heat of hydrogenation for the following compounds is Question structure 1 of 4, ABC26OR0035 Question structure 2 of 4, ABC26OR0035 Question structure 3 of 4, ABC26OR0035 Question structure 4 of 4, ABC26OR0035 (I) (II) (III) (IV)
(a)I $>$ II $>$ III $>$ IV
(b)I $>$ III $>$ II $>$ IV
(c)IV > I > III > II
(d)IV $>$ II $>$ I $>$ III
Answer
Answer: B ✓ checked by 4AB · confidence high
Explanation
The more substituted and the trans alkenes are more stable and so release less heat on hydrogenation. 1-Pentene > cis-2-pentene > trans-2-pentene > 2-methyl-2-butene: I > III > II > IV (b).

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