Q44 · CSIR-NET Chemistry, June 2016

Paper: CSIR-NET June 2016 · Subject: Inorganic Chemistry · Chapter: Inorganic Spectroscopy · Topic: Mossbauer · Marks: 2 · Difficulty: Medium

To record Mossbauer spectrum of Fe containing samples, a source 'X' is used. X after a nuclear transformation (Y), gives $\gamma$-radiation used in Mössbauer spectroscopy.
(a)${ }^{57} \mathrm{Fe}, \beta$-emission
(c)${ }^{57} \mathrm{Co}$, electron capture
(b)${ }^{57} \mathrm{Co}, \beta$-emission
(d)${ }^{57} \mathrm{Fe}$, electron capture
Answer
Answer: B ✓ checked by 4AB · confidence high

The source book printed C; on checking, B is correct — see the explanation.

Explanation
The source is ⁵⁷Co, which decays by electron capture to the 14.4 keV excited state of ⁵⁷Fe, whose γ-ray is used.

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