Consider the following transformation, reactions in the context of co-enzyme B₁₂ (A) 1, 2-Carbon shift (B)… · ABC26IN0048

Subject: Inorganic Chemistry · Chapter: Bioinorganic Chemistry · Topic: Bioinorganic Chemistry – General · Exam: CSIR-NET 2019 · Marks: 2 · Difficulty: Easy

Consider the following transformation, reactions in the context of co-enzyme $\mathrm{B_{12}}$
(A) 1, 2-Carbon shift
(B) Hydration of $\mathrm{CO_2}$
(C) Benzene to phenol
(D) dimethyl sulfide to demethyl sulfoxide
The correct statement(s) for co-enzyme $\mathrm{B_{12}}$ is/are
(a)A, C, D
(b)A, B only
(c)B, C only
(d)A only
Answer
Answer: D ✓ checked by 4AB · confidence medium
Explanation
Coenzyme B₁₂ enzymes catalyse radical 1,2-carbon-skeleton shifts; CO₂ hydration (Zn), arene hydroxylation and sulfoxidation are not B₁₂ chemistry — A only.

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